Assessment of surface ozone over residential environments تقييم الأوزون السطحي على البيئات السکنية

Document Type : Original Article

Abstract

ABSTRACT
Surface ozone (O3) has become one of the most important topic of air quality and climate
change researches. This is because of causing harmful effects on human health, climate, vegetation
and materials. For these reasons, understanding the processes which control the origin, trends,
distribution and effects surface O3 are important. In this paper, the surface O3 concentration was
investigated experimentally and numerically over residential environment. Surface O3 was measured
using Visible blind Ultraviolet sensors (UV Ozone Analyzer) over the period of 2008-2010 in Kuwait
international airport. A back trajectory method based on HYbrid Single-Particle Lagrangian
Integrated Trajectory (HYSPLIT) model was used for assessing the surface O3 over residential
environment. The diurnal, and seasonal variations of surface O3 were analyzed and discussed.
Furthermore, the effect of meteorological conditions on the surface O3 was also analyzed. Diurnal
variation shows that maximum O3 concentration was at the noon and about minimum in the evening.
Seasonal variation showed that February was a highest rate of O3 concentration. Power stations are
a major point source for O3 precursors. The surface O3 shows a medium correlation with
temperature and a week correlation with wind speed
الملخص العربي :
أصبح الأوزون السطحي (O3) أحد أهم موضوعات أبحاث جودة الهواء وتغير المناخ في البيئة
الحضرية. وذلک لأنه يتسبب في آثار ضارة على صحة الإنسان والمناخ والغطاء النباتي والمواد. لهذه الأسباب،
فمن الضروري فهم العمليات التي تتحکم في أصل O3 واتجاهات O3 وتوزيع O3 واثأر O3. ولهذا في البحث
الحالي، يتم دراسة ترکيز O3 عمليا وعدديا على البيئة السکنية. عمليا تم قياس O3 باستخدام أجهزة استشعار الأشعة
فوق البنفسجية المرئية (محلل الأشعة فوق البنفسجية الأوزون) خلال الفترة ٢٠١٠-٢٠٠٨ في مطار الکويت
الدولي. و عدديا تم استخدام طريقة المسار الخلفي على أساس نموذج HYSPLIT لتقييم السطح O3 على البيئة
السکنية. وقد تم تحليل التغيرات النهارية، والموسمية للأوزون السطحي ومناقشتها. وعلاوة على ذلک، تم أيضا
تحليل تأثير الأحوال الجوية على O3. وأظهرت النتائج التباين في ترکيز الأوزون حيث يظهر أقصى ترکيز
للأوزون في الظهر والحد الأدنى للترکيز في المساء. ويظهر التفاوت الموسمي الأعلى معدل لترکيز O3 في
فبراير. وأظهرت النتائج انه يوجد علاقة قوية للأوزون مع درجة الحرارة ومع سرعة الرياح. وأن محطات
الکهرباء تکون المصدر الرئيسي للأوزون .

Highlights

REFERENCES
[1] Zurita, E., and Castro, M. (1982): A
statistical analysis of mean hourly
oncentrations of surface ozone at
Madrid (Spain),, 17(11) 2213–2220.
[2] Shreffler, J.H. and Evans, R.B. (1982):
The surface ozone record from the
regional air pollution study, 1975–1976,
Atmospheric Environment, 16(6),
1311–1321.
[3] Sanhueza, E., Octavio, K., and Arrocha,
A. (1985): Surface ozone measurements
in the Venezuelan tropical Journal of
Atmospheric Chemistry, 2(4) 377-385.
[4] Lefohn A. S., Krupa A.V., and
Winstanley D. (1990): Surface ozone
exposures measured at clean locations
around the world, Environmental
Pollution 63(3), 189-224.
[5] Gehrig, S. W. (1990): studied surface
ozone in rural, urban and alpine regions
of Switzerland, Atmospheric Environment. Part A. General Topics, 24(10) 2641–2646. 

[6] Minoura H. (1999): Some characteristics
of surface ozone concentration observed
in an urban atmosphere, Atmospheric
Research, 51(2) 153–169.

[7] Lal, S., Naja, M., and Subbaraya, B.
h. (2000): Seasonal variations in surface
ozone and its precursors over an urban
site in India, Atmospheric Environment,
34(170), 2713–2724.
[8] Vukovich, F. M., and Sherwell J. (2003):
An examination of the relationship
between certain meteorological
parameters and surface ozone variations
in the Baltimore–Washington corridor,
Atmospheric Environment, 37, 971–
981.
[9] Jaffe, D. and Ray, J.(2007): Increase in
surface ozone at rural sites in the
western US, Atmos. Environ., 41,
5452–5463.
[10] Oltmans, S. J., Lefohn, A. S., Harris, J.
M., and Shadwick, D. S. (2008):
Background ozone levels of air entering
the west coast of the U.S. and
assessment of longer-term changes,
Atmos. Environ.,42, pp. 6020–6038.
[11] Parrish, D. D., Millet, D. B., and
Goldstein, A. H. (2009): Increasing
ozone in marine boundary layer inflow
at the west coasts of North America and
Europe. Atmos. Chem. Phys., 9,
pp.1303-1323.
[12] Kurokawa, J., Ohara, T., Uno, I.,
Hayassaki, M., and Tanimoto.,H.
(2009): Influence of meteorological
variability on interannual variations of
the springtime boundary layer ozone
over Japan during 1981–2005, Atmos.
Chem. Phys., Discus., 2009.
[13] Tanimoto, H. (2009): Increase in
springtime tropospheric ozone at a
mountainous site in Japan for the period
1998–2006, Atmos. Environ.,43,
pp1358–1363.
[14] Fiore, A. M., Jacob, D. J., Logan, J. A.,
and Yin, J. H.(1998): Long-term trends
in ground level ozone over the
contiguous United States,1980–1995, J.
Geophys. Res.-Atmos., 103, pp.1471–
1480.
[15] USEPA (2008): EPA’s Report on the
Environment. EPA/600/R-07/045F,
Washington, DC 20460.
[16] Reddy, R. R., Rama, G. K., Reddy S.S.
L., Narasimhulu, K., Nazeer, A. Y.,
and Rao, T.V.R. (2008): Surface ozone
measurements at Anantapur (AP) India.
Indian Jornal of Radio & space Physics.
37, pp. 209-215.
[17] Im, U., Markakis K, Poupkou A,
Melas D, Unal A, and Gerasopoulos
E. (2011): The impact of temperature
changes on summertime ozone and its'
precursors in the Eastern
Mediterranean. Atmos Chem Phys
2011b;11:3847–64.
[18] Toh, Y.Y., Lim, S.F., and Glasow, R.V.
(2013): The influence of meteorological
factors and biomass burning on surface
ozone concentrations at Tanah Rata,
Malaysia, Atmospheric Environment
70, 435-446.
[19] Tang, G., Li X., Wang, Y., Xin, J., and
Ren, J. (2009): Surface ozone trend
details and interpretations in Beijing
2001–2006. Atmos. Chem. Phys. 9, pp
8813–8823.
[20] Edith, G., Steven, P., ALICE Gilliland,
A., and S. Trivikrama, R. S. (2006):
Observation-Based Assessment of the
Impact of Nitrogen Oxides missions
Reductions on Ozone Air Quality over
the Eastern United States. APPLIED
METEOROLOGY AND
CLIMATOLOGY. 46, pp. 994-1008.
[21] Pires, J.C.M., Alvim-Ferraz , M.C.M.
and Martins , F.G. , (2012): Surface
ozone behavior at rural sites in Portugal,
Atmospheric, 104–105, 164–171
[22] Wang,X., Shen, Z., Cao, J., Zhang, L.,
Liu, L., Li, J., Liu, S., Sun, Y. (2012):
Characteristics of surface ozone at an
urban site of Xi'an in Northwest China.
J Environ Monit, 14(1):116-26.
[23] Akritidis, D., Zanis, P., Katragkou, E.,
Schultz, M.G., Tegoulias, I., Poupkou,
A., Markakis, K., Pytharoulis, I.
Karacostas, Th., (2013): Evaluating

Keywords